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Short-Range and Medium-Range Order in Lithium Silicate Glasses, Part II: Simulation of the Structure by the Reverse Monte Carlo Method

Uhlig, Harald; Hoffmann, Michael J.; Lamparter, Hannes-Peter; Aldinger, Fritz; Bellissent, Robert; Steeb, Siegfried

The results of X-ray and neutron diffraction experiments with
(Li2O)(x)(SiO2)(100-x) glasses (x = 0, 20, 33.3, and 40) are discussed
using the Reverse Monte Carlo method to produce atomic clusters, which
are analyzed with respect to the O-O distribution, the angular
correlations within the first and higher coordination spheres, and the
bond-orientational multipole moments, Within Li2O-containing silicate
glasses, each lithium atom is surrounded by a ring of six SiO4
tetrahedra in such a way that four oxygen atoms lie at the joints of a
tetragonal cell entered by lithium. Thus, the lithium atoms increase
the order of the glass.

Zugehörige Institution(en) am KIT Fakultät für Maschinenbau – Institut für Keramik im Maschinenbau (IKM)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 1996
Sprache Englisch
Identifikator ISSN: 0002-7820
KITopen-ID: 1000007711
Erschienen in Journal of the American Ceramic Society
Verlag American Ceramic Society
Band 79
Heft 11
Seiten 2839-2846
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