Synthesis and Rheology of Model Comb Polymer Architectures
Abstract:
For a better understanding of the extent of branching and its influence on the rheological properties of commercial branched polymers, well-defined linear and branched (comb) model polymers were synthesized. The correlation between the melt rheological properties and the polymer topology was investigated under small amplitude oscillatory shear (SAOS), uniaxial extension and medium- (MAOS) respectively large amplitude oscillatory shear (LAOS) in combination with Fourier-Transform rheology.
| Zugehörige Institution(en) am KIT | Institut für Technische Chemie und Polymerchemie (ITCP) |
| Publikationstyp | Hochschulschrift |
| Publikationsjahr | 2011 |
| Sprache | Englisch |
| Identifikator | urn:nbn:de:swb:90-287811 KITopen-ID: 1000028781 |
| Verlag | Karlsruher Institut für Technologie (KIT) |
| Art der Arbeit | Dissertation |
| Fakultät | Fakultät für Bio- und Geowissenschaften (Fak. f. Bio- u. Geowiss.) |
| Institut | Institut für Technische Chemie und Polymerchemie (ITCP) |
| Prüfungsdaten | 15.12.2011 |
| Schlagwörter | Anionic Polymerization, Polymer Topology, Branched Polymers, Extensional Rheology, Fourier-Transform Rheology |
| Referent/Betreuer | Wilhelm, M. |