KIT | KIT-Bibliothek | Impressum
Open Access Logo
§
Volltext
URN: urn:nbn:de:swb:90-292444

Efficient Switching of RAFT to Hydroxyl Capped Polymers as a Versatile Scaffold for Block Copolymer Synthesis

Schmid, Christina Maria

Abstract:
The RAFT polymerization is a versatile technique to synthesize polymers with narrow dispersity and high chain-end functionality. To enable a switch from RAFT to other polymerization protocols, the RAFT polymers were transformed via a novel end-group conversion into OH functional polymers. The procedure was employed to synthesize a variety of sulfur-free (multi-) block (star) copolymers. The complex polymers were analyzed via LCCC-SEC, SEC/ESI-MS, and SEC/FT-IR.


Zugehörige Institution(en) am KIT Institut für Technische Chemie und Polymerchemie (ITCP)
Publikationstyp Hochschulschrift
Jahr 2012
Sprache Englisch
Identifikator KITopen ID: 1000029244
Verlag Karlsruhe
Abschlussart Dissertation
Fakultät Fakultät für Chemie und Biowissenschaften (CHEM-BIO)
Institut Institut für Technische Chemie und Polymerchemie (ITCP)
Prüfungsdaten 20.07.2012
Referent/Betreuer Prof. C. Barner-Kowollik
Schlagworte Blockcopolymere; RAFT Polymerisation; Endgruppenumwandlung; Ring-öffnende Polymerization; LCCC; 2D LC; SEC/ESI-MS
KIT – Die Forschungsuniversität in der Helmholtz-Gemeinschaft KITopen Landing Page