Quantifying the Reactivity of Photolytically Generated Radicals Towards Vinylic Monomers via Electrospray Ionization-Mass Spectrometry
Abstract:
Exact knowledge of the reactivity of photolytically generated radicals towards initiating free radical polymerization processes is still scarce. In here, quantitative coupled size-exclusion chromatography (SEC) - electrospray ionization-mass spectrometry (ESI-MS) as well as direct infusion ESI-MS was employed to obtain the propensity of variable photolytically generated radical species to initiate macromolecular growth.
| Zugehörige Institution(en) am KIT | Institut für Technische Chemie und Polymerchemie (ITCP) |
| Publikationstyp | Hochschulschrift |
| Publikationsjahr | 2012 |
| Sprache | Englisch |
| Identifikator | urn:nbn:de:swb:90-320090 KITopen-ID: 1000032009 |
| Verlag | Karlsruher Institut für Technologie (KIT) |
| Art der Arbeit | Dissertation |
| Fakultät | Fakultät für Chemie und Biowissenschaften (CHEM-BIO) |
| Institut | Institut für Technische Chemie und Polymerchemie (ITCP) |
| Prüfungsdaten | 19.10.2012 |
| Schlagwörter | Free Radical Polymerization, Photoinitiator, PLP, SEC/ESI-MS |
| Referent/Betreuer | Barner-Kowollik, C. |