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URN: urn:nbn:de:swb:90-465471
Originalveröffentlichung
DOI: 10.1039/C4CP00672K
Scopus
Zitationen: 5
Web of Science
Zitationen: 4

Electrolyte layering at the calcite(104)-water interface indicated by Rb⁺- and Se(VI) K-edge resonant interface diffraction

Heberling, F.; Eng, P.; Denecke, M. A.; Lützenkirchen, J.; Geckeis, H.

Abstract:
Calcite-water interface reactions are of major importance in various environmental settings as well as in industrial applications. Here we present resonant interface diffraction results on the calcite(104)-aqueous solution interface{,} measured in solutions containing either 10 mmol L-1 RbCl or 0.5 mmol L-1 Se(vi). Results indicate that Rb+ ions enter the surface adsorbed water layers and adsorb at the calcite(104)-water interface in an inner-sphere fashion. A detailed analysis based on specular and off-specular resonant interface diffraction data reveals three distinct Rb+ adsorption species: one 1.2 A above the surface{,} the second associated with surface adsorbed water molecules 3.2 A above the surface{,} and the third adsorbed in an outer-sphere fashion 5.6 A above the surface. A peak in resonant amplitude between L = 1.5 and L = 3.0 is interpreted as signal from a layered electrolyte structure. The presence of a layered electrolyte structure seems to be confirmed by data measured in the presence of Se(vi).


Zugehörige Institution(en) am KIT Institut für Nukleare Entsorgung (INE)
Publikationstyp Zeitschriftenaufsatz
Jahr 2014
Sprache Englisch
Identifikator ISSN: 1463-9076
KITopen ID: 1000046547
HGF-Programm 32.27.01; LK 01
Erschienen in Physical Chemistry Chemical Physics
Band 16
Heft 25
Seiten 12782-12792
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