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Reactor modeling to simulate catalytic partial oxidation and steam reforming of methane. Comparison of temperature profiles and strategies for hot spot minimization

Barrio, V. L.; Schaub, G. 1; Rohde, M. 1; Rabe, S.; Vogel, F.; Cambra, J. F.; Arias, P. L.; Güemez, M. B.
1 Engler-Bunte-Institut (EBI), Karlsruher Institut für Technologie (KIT)


Catalytic partial oxidation (CPO) reactions of methane in the presence of steam (low temperature CPO, LTCPO) over a noble metal catalyst were investigated. A quasi-homogeneous one-dimensional model was developed in order to model a lab-scale fixed-bed reactor to produce syngas. These model calculations can contribute to the optimization of the process with respect to the formation of important hot spots (ΔT⩾130∘)(ΔT⩾130∘). These useful data can enable the model development in order to study the influence of the space velocity, product composition and other variables. Furthermore, a feed splitting study was performed. In the heat balance an overall heat transport term was included to account for small heat losses/gains along the reactor. The agreement between simulations and the degree of detail in the model is appropriate for the amount and kind of experimental data available. Thus, this model can also assist in a pilot reactor design, materials and further scale-up.

DOI: 10.1016/j.ijhydene.2006.10.022
Zitationen: 60
Web of Science
Zitationen: 58
Zitationen: 54
Zugehörige Institution(en) am KIT Engler-Bunte-Institut (EBI)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2007
Sprache Englisch
Identifikator ISSN: 0360-3199
KITopen-ID: 1000050242
Erschienen in International Journal of Hydrogen Energy
Verlag Elsevier
Band 32
Heft 10-11
Seiten 1421-1428
Nachgewiesen in Scopus
Web of Science
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