A reversible wetting transition in strontium titanate and its influence on grain growth and the grain boundary mobility

The impact of the oxygen partial pressure on grain growth in high purity strontium titanate is evaluated by observing microstructures, the grain growth constant k and the relative mobility of strontium titanate. The microstructures indicate a reversible wetting transition between 1460 C and 1500 C. The wetting second phase is titania-rich and free from any detectable solutes. Exaggerated grain growth was found close to the wetting transition and is explained by a temperature dependent anisotropy of the grain boundary mobility in conjunction with a high mobility of wetted grain boundaries. The grain growth constant in reducing atmosphere shows two transitions at 1350 C and at 1460 C. At the first transition the grain growth constant decreases with temperature. A strong increase of k with temperature at the second transition is attributed to the wetting transition. The relative grain boundary mobility of different orientations ({100}, {110}, {111}, and {310}) was measured in oxidizing and reducing atmosphere by observing the growth of oriented single crystals into polycrystals. At 1550 C in reducing atmosphere the wetting liquid phase enhances the mobility by a factor of 10 compared to oxidizing atmosphere. ... mehrAdditionally, the atmosphere changes grain growth kinetics: in oxidizing, but not in reducing atmosphere growth stagnation occurs for long dwell times.