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Extraordinary Performance of Carbon-Coated Anatase TiO2 as Sodium-Ion Anode

Tahir, M.N.; Oschmann, B.; Buchholz, D.; Dou, X.; Lieberwirth, I.; Panthöfer, M.; Tremel, W.; Zentel, R.; Passerini, S.

Abstract (englisch):
The synthesis of in situ polymer-functionalized anatase TiO2 particles using an anchoring block copolymer with hydroxamate as coordinating species is reported, which yields nanoparticles (≈11 nm) in multigram scale. Thermal annealing converts the polymer brushes into a uniform and homogeneous carbon coating as proven by high resolution transmission electron microscopy and Raman spectroscopy. The strong impact of particle size as well as carbon coating on the electrochemical performance of anatase TiO2 is demonstrated. Downsizing the particles leads to higher reversible uptake/release of sodium cations per formula unit TiO2 (e.g., 0.72 eq. Na+ (11 nm) vs only 0.56 eq. Na+ (40 nm)) while the carbon coating improves rate performance. The combination of small particle size and homogeneous carbon coating allows for the excellent electrochemical performance of anatase TiO2 at high (134 mAh g−1 at 10 C (3.35 A g−1)) and low (≈227 mAh g−1 at 0.1 C) current rates, high cycling stability (full capacity retention between 2nd and 300th cycle at 1 C) and improved coulombic efficiency (≈99.8%).

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Volltext §
DOI: 10.5445/IR/1000053114
DOI: 10.1002/aenm.201501489
Zitationen: 109
Web of Science
Zitationen: 108
Zugehörige Institution(en) am KIT Helmholtz-Institut Ulm (HIU)
Publikationstyp Zeitschriftenaufsatz
Jahr 2016
Sprache Englisch
Identifikator ISSN: 1614-6832, 1614-6840
KITopen-ID: 1000053114
HGF-Programm 37.01.01 (POF III, LK 01)
Erschienen in Advanced energy materials
Band 6
Heft 4
Seiten 1501489/1-9
Schlagworte anatase TiO2, carbon coating, nanoparticles, RAFT polymerization, sodium-ion batteries
Nachgewiesen in Web of Science
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