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Investigation of Binary Mixtures Containing 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)azanide and Ethylene Carbonate

Hofmann, A. ORCID iD icon 1; Migeot, M. 1; Hanemann, T. 1
1 Institut für Angewandte Materialien – Werkstoffkunde (IAM-WK), Karlsruher Institut für Technologie (KIT)


Temperature dependent viscosity, conductivity, and density data of binary mixtures containing ethylene carbonate (EC) and 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)azanide (EMIM-TFSA) were determined at atmospheric pressure in a wide temperature range of (20 to 120) °C. Additionally, differential scanning calorimetry (DSC) measurements were performed from (−120 to +100) °C to characterize phase behavior of the mixtures. On the basis of the experimental data it is demonstrated that the lattice hole theory can be applied excellently to the conductivity data of the binary mixture EMIM-TFSA/EC. The viscosity data were fitted according to the Vogel–Fulcher–Tammann–Hesse (VFTH) equation and analyzed with the help of the fractional Walden rule. It is concluded that the mixtures can be classified as fragile according to ionicity. The aim of the study is to present fundamental physicochemical data about the mixtures as a basis for structure–property relationship-calculations of solvent mixtures or use as electrolytes for various applications.

Volltext §
DOI: 10.5445/IR/1000053149
DOI: 10.1021/acs.jced.5b00338
Zitationen: 29
Web of Science
Zitationen: 30
Zitationen: 29
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Angewandte Materialien – Werkstoffkunde (IAM-WK)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2016
Sprache Englisch
Identifikator ISSN: 0021-9568
KITopen-ID: 1000053149
HGF-Programm 37.01.11 (POF III, LK 01) Elektrochemistry, Theory and Modelling
Erschienen in Journal of Chemical and Engineering Data
Verlag American Chemical Society (ACS)
Band 61
Heft 1
Seiten 114-123
Nachgewiesen in Web of Science
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