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Synthesis, structural characterisation and proton conduction of two new hydrated phases of barium ferrite BaFeO2.5-x(OH)₂ₓ

Knöchel, P.L.; Keenan, P.J.; Loho, C.; Reitz, C.; Witte, R.; Knight, K.S.; Wright, A.J.; Hahn, H.; Slater, P.R.; Clemens, O.

Abstract (englisch):
Materials exhibiting mixed electronic and proton conductivity are of great interest for applications ranging from electrodes for proton conducting ceramic fuel cells to hydrogen separation membranes. In this work, we report a detailed investigation of the effect of water incorporation in BaFeO2.5 on the structure and conductivity. BaFeO2.5 is shown to be topochemically transformed to two different hydrated modifications, low-water (LW-) and high-water (HW-) BaFeO2.5. A combined analysis of neutron and X-ray diffraction data was used to determine the crystal structure of LW-BaFeO2.5 (BaFeO2.33(OH)0.33), which shows a unique ordering pattern of anion vacancies for perovskite type compounds, with structural relaxations around vacancies being similar to the chemically similar compound BaFeO2.33F0.33. Approximate proton positions were determined using the bond valence method. Conductivity studies of hydrated and pure BaFeO2.5 (with additional comparison to oxidized BaFeO2.5) show a significant enhancement of the conductivity on water incorporation, which can be attributed to proton conductivity. This is the first report of significant grain proton conduction (∼10−6 to 10−7 S cm−1) in an iron based perovskite. ... mehr

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DOI: 10.1039/c5ta06383c
Zitationen: 12
Web of Science
Zitationen: 12
Zugehörige Institution(en) am KIT Institut für Nanotechnologie (INT)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2016
Sprache Englisch
Identifikator ISSN: 2050-7488
KITopen-ID: 1000053818
HGF-Programm 43.22.01 (POF III, LK 01)
Functionality by Design
Erschienen in Journal of Materials Chemistry A
Band 4
Heft 9
Seiten 3415-3430
Nachgewiesen in Scopus
Web of Science
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