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Bimetallic rare-earth/platinum complexes ligated by phosphinoamides

Völcker, Franziska; Roesky, Peter W.

Abstract: The heterometallic early-late 5d/4f binuclear phosphinoamido Ln/Pt(0) complexes [(Ph2PNHPh)Pt{μ-(Ph2PNPh)}3Ln(μ-Cl)Li(THF)3] (Ln = Y (1a), Lu (1b)) were obtained by reaction of [Li(THF)4][(Ph2PNPh)4Ln] (Ln = Y, Lu) with the Pt(0) complex [Pt(tBu3P)2] in the presence of LiCl. In the absence of LiCl the corresponding Ln/Pt(0) complexes [(Ph2PNHPh)Pt{μ-(Ph2PNPh)}3Ln{η2-(Ph2PNPh)}][Li(THF)4] (Ln = Y (2a), Lu (2b)) were isolated. Both kind of complexes decompose in solution. The Pt(0) complex [Pt(Ph2PNHPh)4] (3) was identified as one of these decomposition products.


Zugehörige Institution(en) am KIT Institut für Anorganische Chemie (AOC)
Publikationstyp Zeitschriftenaufsatz
Jahr 2016
Sprache Englisch
Identifikator DOI: 10.1039/C6DT00417B
ISSN: 0300-9246, 1364-5447, 1470-479X, 1472-7773, 1477-9226, 1477-9234
URN: urn:nbn:de:swb:90-545104
KITopen ID: 1000054510
Erschienen in Dalton transactions
Band 45
Heft 23
Seiten 9429-9435
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