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Microwave Crystallization of Lithium Aluminum Germanium Phosphate Solid-State Electrolyte

Mahmoud, M.M.; Cui, Y.; Rohde, M.; Ziebert, C.; Link, G.; Seifert, H.J.

Abstract (englisch):
Lithium aluminum germanium phosphate (LAGP) glass-ceramics are considered as promising solid-state electrolytes for Li-ion batteries. LAGP glass was prepared via the regular conventional melt-quenching method. Thermal, chemical analyses and X-ray diffraction (XRD) were performed to characterize the prepared glass. The crystallization of the prepared LAGP glass was done using conventional heating and high frequency microwave (MW) processing. Thirty GHz microwave (MW) processing setup were used to convert the prepared LAGP glass into glass-ceramics and compared with the conventionally crystallized LAGP glass-ceramics that were heat-treated in an electric conventional furnace. The ionic conductivities of the LAGP samples obtained from the two different routes were measured using impedance spectroscopy. These samples were also characterized using XRD and scanning electron microscopy (SEM). Microwave processing was successfully used to crystallize LAGP glass into glass-ceramic without the aid of susceptors. The MW treated sample showed higher total, grains and grain boundary ionic conductivities values, lower activation energy and relatively larger-grained microstructure with less porosity compared to the corresponding conventionally treated sample at the same optimized heat-treatment conditions. ... mehr

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DOI: 10.5445/IR/1000055865
DOI: 10.3390/ma9070506
Zitationen: 9
Web of Science
Zitationen: 10
Zitationen: 10
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Angewandte Materialien - Angewandte Werkstoffphysik (IAM-AWP)
Institut für Hochleistungsimpuls- und Mikrowellentechnik (IHM)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2016
Sprache Englisch
Identifikator ISSN: 1996-1944
KITopen-ID: 1000055865
HGF-Programm 37.01.02 (POF III, LK 01) Components and Cells
Erschienen in Materials
Verlag MDPI
Band 9
Heft 7
Seiten 506
Bemerkung zur Veröffentlichung Gefördert durch den KIT-Publikationsfonds
Schlagwörter microwaves; crystallization; LAGP; ionic conductivity; solid-state electrolyte; Li-ion batteries
Nachgewiesen in Scopus
Web of Science
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