Thin Films of Porphyrin-Based Metal-Organic Frameworks Grown by Liquid-Phase Epitaxy
Abstract:
Porphyrin-based surface-mounted metal-organic frameworks (SURMOFs) were synthesized via liquid-phase epitaxy method, which were assembled into photovoltaic devices to investigate the photoconductivity and power conversion efficiency. Subsequently, the porphyrin-based surface-grafted gel (SURGEL) was synthesized from azido-porphyrin SURMOF by post-synthetic modification. Finally, liquid- and gas -phase diffusion in HKUST-1 SURMOF was investigated with a quartz crystal microbalance (QCM).
| Zugehörige Institution(en) am KIT | Institut für Funktionelle Grenzflächen (IFG) |
| Publikationstyp | Hochschulschrift |
| Publikationsjahr | 2016 |
| Sprache | Englisch |
| Identifikator | urn:nbn:de:swb:90-578239 KITopen-ID: 1000057823 |
| Verlag | Karlsruher Institut für Technologie (KIT) |
| Umfang | iii, IV, 131 S. |
| Art der Arbeit | Dissertation |
| Fakultät | Fakultät für Chemie und Biowissenschaften (CHEM-BIO) |
| Prüfungsdaten | 22.07.2016 |
| Schlagwörter | Surface-mounted metal-organic frameworks, Porphyrins, Photovoltaic, Surface-grafted gels, Diffusion |
| Referent/Betreuer | Wöll, C. |