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Impact of laterite characteristics on fluoride removal from water

Osei, J.; Gawu, S. K. Y.; Schäfer, A. I. 1; Atipoka, F.; Momade, F. W. Y.
1 Fakultät für Chemieingenieurwesen und Verfahrenstechnik (CIW), Karlsruher Institut für Technologie (KIT)

Abstract (englisch):


The presence of high concentrations of fluoride in groundwater is a threat to the provision of potable water especially to rural communities. Various substances have been suggested for the removal of fluoride from water. This work investigates the characteristics of laterite, which makes it an adsorbent applicable to fluoride removal.


Chemical and mineralogical analyses of the laterite using X-ray fluorescence (XRF) and X-ray diffraction (XRD) techniques showed varying amounts of iron oxide/hydroxide (goethite/hematite), silica (quartz) and kaolinite. Scanning electron microscopy (SEM) combined with energy dispersive X-ray (EDX) analysis revealed intimate association of all minerals. Isoelectronic point (IEP) value was largely influenced by the mineralogical composition with higher values for higher iron oxide/hydroxide content.


While variation in the initial pH of fluoride solution had an effect on fluoride adsorption, the impact of IEP (and hence indirectly pHpzc) was not significant in adsorption. Samples heat treated at 400 °C performed better in fluoride adsorption. The mechanism for fluoride adsorption in this study was attributed to two processes: (i) ion exchange between hydroxide ion of the laterite surface and fluoride ion in solution; and (ii) fluoride uptake by specific surface reactions involving H3O+F− which leads to the release of hydroxonium (H3O+) ions in solution. ... mehr

DOI: 10.1002/jctb.4656
Zitationen: 22
Web of Science
Zitationen: 19
Zitationen: 22
Zugehörige Institution(en) am KIT Institute for Advanced Membrane Technology (IAMT)
Institut für Funktionelle Grenzflächen (IFG)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2016
Sprache Englisch
Identifikator ISSN: 0021-8871, 0142-0356, 0268-2575, 0368-4075, 0375-9210, 1097-4660
KITopen-ID: 1000060458
HGF-Programm 12.02.03 (POF III, LK 01) Regional Climate-and Water Cycle Variab.
Erschienen in Journal of chemical technology & biotechnology
Verlag John Wiley and Sons
Heft 91
Seiten 911 - 920
Schlagwörter laterite; chemical; mineralogical; fluoride adsorption; mechanism pH
Nachgewiesen in Dimensions
Web of Science
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