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Modelling of Innovative SANEX Process Maloperations

McLachlan, Fiona; Taylor, Robin; Whittaker, Daniel; Woodhead, David; Geist, Andreas ORCID iD icon

Abstract (englisch):

The innovative (i-) SANEX process for the separation of minor actinides from PUREX highly active raffinate is expected to employ a solvent phase comprising 0.2M TODGA with 5 v/v% 1-octanol in an inert diluent. An initial extract / scrub section would be used to extract trivalent actinides and lanthanides from the feed whilst leaving other fission products in the aqueous phase, before the loaded solvent is contacted with a low acidity aqueous phase containing a sulphonated bis-triazinyl pyridine ligand (BTP) to effect a selective strip of the actinides, so yielding separate actinide (An) and lanthanide (Ln) product streams. This process has been demonstrated in lab scale trials at Jülich (FZJ).

The SACSESS (Safety of ACtinide SEparation proceSSes) project is focused on the evaluation and improvement of the safety of such future systems. A key element of this is the development of an understanding of the response of a process to maloperations. It is only practical to study a small subset of possible maloperations experimentally and consideration of the majority of maloperations entails the use of a validated dynamic model of the process.
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Volltext §
DOI: 10.5445/IR/1000062643
DOI: 10.1016/j.proche.2016.10.016
Zitationen: 5
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Nukleare Entsorgung (INE)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2016
Sprache Englisch
Identifikator ISSN: 1876-6196
KITopen-ID: 1000062643
HGF-Programm 32.01.11 (POF III, LK 01) Extraktions- und Koordinationschemie der Actiniden
Erschienen in Procedia chemistry
Verlag Elsevier
Band 21
Seiten 109–116
Bemerkung zur Veröffentlichung ATALANTE 2016 International Conference on Nuclear Chemistry for Sustainable Fuel Cycles
Schlagwörter TODGA; innovative SANEX; i-SANEX; process modelling; maloperation; minor actinide; lanthanide; americium; europium; solvent extraction
Nachgewiesen in Dimensions
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