Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol-yne reaction
Abstract:
Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol-yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.
| Zugehörige Institution(en) am KIT | Institut für Toxikologie und Genetik (ITG) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2016 |
| Sprache | Englisch |
| Identifikator | ISSN: 1860-5397 urn:nbn:de:swb:90-629268 KITopen-ID: 1000062926 |
| HGF-Programm | 47.01.01 (POF III, LK 01) Biol.Netzwerke u.Synth.Regulat. ITG+ITC |
| Erschienen in | Beilstein journal of organic chemistry |
| Verlag | Beilstein-Institut |
| Band | 12 |
| Seiten | 2570-2576 |
| Vorab online veröffentlicht am | 29.11.2016 |
| Schlagwörter | three-dimensional, porous hyper-crosslinked polymers, thiol–yne |
| Nachgewiesen in | Dimensions Web of Science Scopus |