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URN: urn:nbn:de:swb:90-629268

Synthesis of three-dimensional porous hyper-crosslinked polymers via thiol-yne reaction

Lang, Mathias; Schade, Alexandra; Bräse, Stefan

Abstract:
Herein we report the syntheses of two porous hyper-crosslinked polymers (HCPs) via thiol-yne reaction with rigid tetrahedral and pseudo-octahedral core structures. Sorption measurements with nitrogen gas at 77 K revealed BET-surface areas up to 650 m²/g. Those networks also showed a high thermal stability as well as insolubility in common organic solvents.


Zugehörige Institution(en) am KIT Institut für Toxikologie und Genetik (ITG)
Publikationstyp Zeitschriftenaufsatz
Jahr 2016
Sprache Englisch
Identifikator ISSN: 1860-5397
KITopen ID: 1000062926
HGF-Programm 47.01.01; LK 01
Erschienen in Beilstein journal of organic chemistry
Band 12
Seiten 2570-2576
Schlagworte three-dimensional, porous hyper-crosslinked polymers, thiol–yne
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