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Originalveröffentlichung
DOI: 10.1109/3M-NANO.2016.7824954

Laser-Induced Breakdown Spectroscopy as a Powerful Tool for Characterization of Laser Modified Composite Materials

Smyrek, Peter; Zheng, Yijing; Seifert, H.J.; Pfleging, Wilhelm

Abstract (englisch):
Laser-Induced Breakdown Spectroscopy (LIBS) was applied in order to investigate the elemental composition in laser modified battery materials. In a first approach, thick film electrodes – all incorporating the same active material (lithium nickel manganese cobalt oxide (Li(Ni1/3Mn1/3Co1/3)O2, NMC)) - were manufactured using the tape-casting technique. In a further approach, femtosecond (fs) laser radiation was used for the generation of three dimensional (3D) micro-structures. 3D micro-grids were successfully implemented into thick film electrodes applying a fs-laser wavelength of 515 nm. The electrochemical performance in lithium-ion cells with untreated and laser-modified NMC electrodes was determined by galvanostatic cycling at high charging- and discharging currents. Finally, LIBS was used as a powerful characterization tool in order to investigate the change in lithium distribution after electrochemical cycling at different State-of-Health. Evaluation of lithium distribution will be used to analyze degradation mechanisms and to find the most appropriate 3D electrode architecture. For this purpose, results of electrochemical cyc ... mehr


Zugehörige Institution(en) am KIT Institut für Angewandte Materialien - Angewandte Werkstoffphysik (IAM-AWP)
Karlsruhe Nano Micro Facility (KNMF)
Publikationstyp Proceedingsbeitrag
Jahr 2016
Sprache Englisch
Identifikator DOI(KIT): 10.5445/IR/1000063216
ISBN: 978-1-5090-2945-7
URN: urn:nbn:de:swb:90-632165
KITopen ID: 1000063216
HGF-Programm 37.01.02; LK 01
Erschienen in 6th International Conference on Manipulation, Manufacturing and Measurement on the Nanoscale, (3M-NANO) 18-22 July 2016, Chongqing, China
Verlag IEEE, Piscataway (NY)
Seiten 164-167
Schlagworte Laser-induced breakdown spectroscopy, ultrafast laser structuring, lithium-ion battery, lithium nickel manganese cobalt oxide, cathode
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