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Ion-redistribution induced efficient upconversion in β-NaYF_4:20%Yb^3+,2%Er^3+ microcrystals with well controlled morphology and size

Fan, Shaohua; Wang, Shikai; Yu, Lu; Sun, Hongtao; Gao, Guojun; Hu, Lili

Abstract (englisch): We develop an efficient green upconversion (UC) β-NaYF4:20%Yb3+,2%Er3+ microcrystal with well controlled morphology and size by hydrothermal method using two different chelating agents of CIT and EDTA-2Na via a simple ion-exchange reaction. Importantly, the UC emission efficiency of newly developed CIT and EDTA-2Na β-NaYF4:20%Yb3+,2%Er3+ microcrystals is almost as strong as that of commercial counterpart by solid-state method. A proof-of-concept β-NaYF4:20%Yb3+,2%Er3+ microcrystal waveguide is demonstrated to extend their applications in modern micro-optoelectronics. The local ion-redistribution process during the ion-exchange reaction, which effectively disperses the locally clustered Yb3+, accounts for the enormously enhanced UC emission in β-NaYF4:20%Yb3+,2%Er3+ microcrystals.

Zugehörige Institution(en) am KIT Institut für Mikrostrukturtechnik (IMT)
Publikationstyp Zeitschriftenaufsatz
Jahr 2017
Sprache Englisch
Identifikator DOI: 10.1364/OE.25.000180
ISSN: 1094-4087
KITopen ID: 1000065505
HGF-Programm 43.23.04; LK 01
Erschienen in Optics express
Band 25
Heft 1
Seiten 180
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