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Bio-inspired micro-to-nanoporous polymers with tunable stiffness

Syurik, Julia; Schwaiger, Ruth; Sudera, Prerna; Weyand, Stephan; Johnsen, Siegbert; Wiegand, Gabriele; Hölscher, Hendrik

Abstract (englisch):
Background: Inspired by structural hierarchies and the related excellent mechanical properties of biological materials, we created a smoothly graded micro- to nanoporous structure from a thermoplastic polymer.

Results: The viscoelastic properties for the different pore sizes were investigated in the glassy regime by dynamic flat-punch indentation. Interestingly, the storage modulus was observed to increase with increasing pore-area fraction.

Conclusion: This outcome appears counterintuitive at first sight, but can be rationalized by an increase of the pore wall thickness as determined by our quantitative analysis of the pore structure. Therefore, our approach represents a non-chemical way to tune the elastic properties and their local variation for a broad range of polymers by adjusting the pore size gradient.


Zugehörige Institution(en) am KIT Institut für Katalyseforschung und -Technologie (IKFT)
Institut für Mikrostrukturtechnik (IMT)
Karlsruhe Nano Micro Facility (KNMF)
Institut für Angewandte Materialien - Werkstoff- und Biomechanik (IAM-WBM)
Publikationstyp Zeitschriftenaufsatz
Jahr 2017
Sprache Englisch
Identifikator ISSN: 2190-4286
KITopen ID: 1000069252
HGF-Programm 43.22.01; LK 01
Erschienen in Beilstein journal of nanotechnology
Band 8
Seiten 906–914
Bemerkung zur Veröffentlichung http://www.beilstein-journals.org/bjnano/articles/8/92
Schlagworte biomimetics; polymeric materials; supercritical carbon dioxide (SC-CO2); tunable storage modulus
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