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Bio-inspired hierarchical micro- and nano-wrinkles obtained via mechanically directed self-assembly on shape-memory polymers

Schauer, Senta; Worgull, Matthias; Hölscher, Hendrik

Inspired by complex multi-functional leaf and petal surfaces, we introduce a mechanically directed self-assembly process to create linearly oriented micro- and nanosized surface wrinkles in an all-polymer bi-layer system based on a shape-memory polymer substrate. By systematically investigating the influence of coating thickness and substrate programming strain on wrinkle period and height, we reveal how to control the structure size from a few hundred nanometers up to several microns. As a parameter unique to shape memory polymers, we demonstrate that the temperature during the recovery process can also be utilized to tailor the structure dimensions. Furthermore, we advance the method with a second structuring step to mimic the hierarchically structured petal surfaces of tulips and daisies. The presented structuring method provides a large-scale, mold-free, and very cost-effective way for the full-polymer fabrication of micro and sub-microstructures with adjustable structure size and intrinsic irregularity.

DOI: 10.1039/C7SM00154A
Zitationen: 18
Web of Science
Zitationen: 18
Zugehörige Institution(en) am KIT Institut für Mikrostrukturtechnik (IMT)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2017
Sprache Englisch
Identifikator ISSN: 1744-683X, 1744-6848
KITopen-ID: 1000071246
HGF-Programm 43.22.01 (POF III, LK 01)
Functionality by Design
Erschienen in Soft matter
Band 13
Heft 24
Seiten 4328-4334
Schlagwörter 2015-014-007111 AFM HE
Nachgewiesen in Web of Science
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