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Verlagsausgabe
DOI: 10.5445/IR/1000083230
Veröffentlicht am 01.08.2018
Originalveröffentlichung
DOI: 10.1007/s10562-018-2432-2

Chemical Reactions at Isolated Single-Sites Inside Metal–Organic Frameworks

Wang, Yuemin; Wöll, Christof

Abstract:
Isolated, coordinatively unsaturated metal sites within metal–organic framework (MOF) materials feature interesting chemical properties and offer applications as single-site catalysts. Here, we report on the recent progress in providing fundamental insight into chemical reactions occurring inside MOFs. In addition to the common form, powders, we discuss the potential of MOF thin films (SURMOFs). The combined spectroscopic and modeling approach applied to selected systems demonstrated that the catalytic activity of MOFs can be precisely tuned. A particular interesting case is the so-called defect-engineering, where structural imperfections are created in a controlled fashion. The chemical properties of MOF materials can be further modified by integration and decoration of linkers or loading with guest species, such as metal or metal–oxide nanoparticles or nanoclusters. A particularly interesting aspect of layer-by-layer approaches for the fabrication of MOF thin films is the prospect to realize tandem catalysts.


Zugehörige Institution(en) am KIT Institut für Funktionelle Grenzflächen (IFG)
Publikationstyp Zeitschriftenaufsatz
Jahr 2018
Sprache Englisch
Identifikator ISSN: 1011-372X, 1572-879X
URN: urn:nbn:de:swb:90-832309
KITopen ID: 1000083230
HGF-Programm 43.22.02; LK 01
Erschienen in Catalysis letters
Band 148
Heft 8
Seiten 2201-2222
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