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Laser micro structuring of composite Li (Ni0.6Mn0.2Co0.2) O2cathode layersfor lithium-ion batteries

Rakebrandt, J.-H.; Smyrek, P.; Zheng, Y.; Seifert, H.J.; Pfleging, W.

Abstract (englisch):
Lithium-ion batteries (LIB) using lithium nickel manganese cobalt oxide Li(Ni1/3Mn1/3Co1/3)O2, NMC-111) as cathode material have already become one of the most important types of mobile power sources due to their high gravimetric and volumetric capacity. Nevertheless, the automotive industry needs batteries with a further improved energy density to develop electric vehicles (EV) with comparable or even higher range than automobiles with ICE (Internal combustion engine). One approach to enhance the energy density is to increase the nickel content of the NMC cathode material. Therefore, NMC-622 cathodes were produced via tape casting containing 80 wt% of active material with a film thickness of 54 μm. The specific capacities were measured using galvanostatic measurements at different charging/discharging currents for cells with structured and unstructured electrodes. Laser-assisted generation of threedimensional architectures provides an increased active surface area to enhance interfacial kinetics with short lithium-ion diffusion paths. Ultrafast laser ablation was used in order to avoid a thermal-induced damage of the active material. ... mehr

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Postprint §
DOI: 10.5445/IR/1000085851
Veröffentlicht am 09.02.2019
Originalveröffentlichung
DOI: 10.1109/3M-NANO.2017.8286297
Coverbild
Zugehörige Institution(en) am KIT Institut für Angewandte Materialien - Angewandte Werkstoffphysik (IAM-AWP)
Karlsruhe Nano Micro Facility (KNMF)
Publikationstyp Proceedingsbeitrag
Jahr 2018
Sprache Englisch
Identifikator ISBN: 978-1-5386-1082-4
urn:nbn:de:swb:90-858514
KITopen-ID: 1000085851
HGF-Programm 37.01.02 (POF III, LK 01)
Erschienen in 2017 IEEE International Conference on Manipulation, Manufacturing and Measurement on the Nanoscale (3M-NANO), Shanghai, China, 7–11 August 2017
Verlag IEEE, Piscataway (NJ)
Seiten 57–60
Projektinformation FabSurfWAR (EU, H2020, 644971)
Schlagworte lithium-ion battery, lithium nickel manganese cobalt oxide, battery performance, laser structuring, ultrafast laser, 3D battery, nickel-rich NMC, high power battery, Proposal-ID: 2016-016-014150 (KNMF-LMP)
Nachgewiesen in Scopus
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