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Verlagsausgabe
DOI: 10.5445/IR/1000087387
Veröffentlicht am 12.11.2018
Originalveröffentlichung
DOI: 10.3390/ma11112134

Carbon Dioxide Hydrogenation by Means of Plasmonic Resonance Activation in Silica Aerogel Media

Muñoz, Sergio; Navarrete, Alexander; Martín, Ángel; Dittmeyer, Roland; Cocero, M.

Abstract:
Surface Plasmon Resonance can be used to activate zinc oxide/copper catalysts in order to perform the carbon dioxide hydrogenation reaction by means of light energy, avoiding high-temperature processes. The synthesis and impregnation methods have been designed to fill glass microreactors with ZnO/Cu nanoparticles supported on transparent silica aerogels to maximize the light absorbed by the catalyst. A LED device surrounding the glass microreactors provided white light to activate the catalyst homogeneously throughout the reactor. Temperature, pressure, amount of catalyst and gases flow were studied as possible variables to enhance the process trying to maximize CO2 conversion rates, achieving the best results working at high pressures. The use of transparent SiO2 Aerogels as supports for photocatalytic gas phase reactions even under high-pressure conditions is demonstrated.


Zugehörige Institution(en) am KIT Institut für Mikroverfahrenstechnik (IMVT)
Publikationstyp Zeitschriftenaufsatz
Jahr 2018
Sprache Englisch
Identifikator ISSN: 1996-1944
URN: urn:nbn:de:swb:90-873873
KITopen-ID: 1000087387
Erschienen in Materials
Band 11
Heft 11
Seiten Article: 2134
Bemerkung zur Veröffentlichung Gefördert durch den KIT-Publikationsfonds
Vorab online veröffentlicht am 30.10.2018
Schlagworte CO2 hydrogenation; photocatalysis; surface plasmon resonance; solar fuels
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