Redox-responsive phosphonite gold complexes in hydroamination catalysis
Abstract:
Very high activities were observed in the redox-induced hydroamination of alkynes by employing a redox-active gold(I) complexfeaturingan electron-deficient, terphenyl-substituted phosphonite-based ligand. The hydroamination proceeds roughly two-fold faster with the in situ oxidized catalysts than with their reduced form.
| Zugehörige Institution(en) am KIT | Institut für Anorganische Chemie (AOC) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2019 |
| Sprache | Englisch |
| Identifikator | ISSN: 0009-241X, 0022-4936, 1359-7345, 1364-548X, 2050-5620, 2050-5639 KITopen-ID: 1000095202 |
| Erschienen in | Chemical communications |
| Verlag | Royal Society of Chemistry (RSC) |
| Band | 55 |
| Heft | 37 |
| Seiten | 5323-5326 |
| Vorab online veröffentlicht am | 20.03.2019 |
| Nachgewiesen in | Web of Science Scopus Dimensions |