Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls
Yadav, Ravi 1; Simler, Thomas 1; Gamer, Michael T. 1; Köppe, Ralf 1; Roesky, Peter W.
1
1 Institut für Anorganische Chemie (AOC), Karlsruher Institut für Technologie (KIT)
11 Institut für Anorganische Chemie (AOC), Karlsruher Institut für Technologie (KIT)
Abstract:
The reduction of M$_{2}$(CO)$_{10}$ (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.
| Zugehörige Institution(en) am KIT | Institut für Anorganische Chemie (AOC) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2019 |
| Sprache | Englisch |
| Identifikator | ISSN: 0009-241X, 0022-4936, 1359-7345, 1364-548X, 2050-5620, 2050-5639 KITopen-ID: 1000095689 |
| Erschienen in | Chemical communications |
| Verlag | Royal Society of Chemistry (RSC) |
| Band | 55 |
| Heft | 41 |
| Seiten | 5765-5768 |
| Nachgewiesen in | OpenAlex Web of Science Scopus Dimensions |