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Rhenium is different: CO tetramerization induced by a divalent lanthanide complex in rhenium carbonyls

Yadav, Ravi; Simler, Thomas; Gamer, Michael T.; Köppe, Ralf; Roesky, Peter W.

Abstract:
The reduction of M$_{2}$(CO)$_{10}$ (M = Mn, Re) with different divalent lanthanide (Ln = Sm, Yb) compounds was investigated. Depending on the steric demand of the ligand, either unusual CO tetramerization or formation of a new Re carbonyl anion occurred in the case of Re. Theoretical calculations were performed for a better understanding of the nature of bonding in the newly formed species.

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Verlagsausgabe §
DOI: 10.5445/IR/1000095689
Veröffentlicht am 28.06.2019
Coverbild
Zugehörige Institution(en) am KIT Institut für Anorganische Chemie (AOC)
Publikationstyp Zeitschriftenaufsatz
Jahr 2019
Sprache Englisch
Identifikator ISSN: 0009-241X, 0022-4936, 1359-7345, 1364-548X, 2050-5620, 2050-5639
KITopen-ID: 1000095689
Erschienen in Chemical communications
Band 55
Heft 41
Seiten 5765-5768
Nachgewiesen in Scopus
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