Boosting axiality in stable high-coordinate Dy(III) single-molecule magnets
Abstract:
A new nine-coordinate, air-stable Dy (III) single-ion magnet has been successfully isolated. Our in silico studies demonstrate that through carefully modulating the ligand electronics, the axiality can be boosted to generate U$_{cal}$ barriers of over 600 K.
| Zugehörige Institution(en) am KIT | Institut für Nanotechnologie (INT) Physikalisches Institut (PHI) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2019 |
| Sprache | Englisch |
| Identifikator | ISSN: 0009-241X, 0022-4936, 1359-7345, 1364-548X, 2050-5620, 2050-5639 KITopen-ID: 1000095696 |
| HGF-Programm | 43.21.02 (POF III, LK 01) Quantum Properties of Nanostructures |
| Erschienen in | Chemical communications |
| Verlag | Royal Society of Chemistry (RSC) |
| Band | 55 |
| Heft | 42 |
| Seiten | 5950-5953 |
| Nachgewiesen in | Dimensions Scopus Web of Science |