Analysis of CH$_{2}$O x OH as marker for fuel-rich air to pure oxy-fuel flames under higher preheat temperature and elevated pressure

The scope of the present work is a numerical and experimental investigation about the range of validity in terms of applicability of CH$_{2}$OxOH as a marker for the heat release rate (HRR) for fuel-rich air to pure oxy-fuel flames including preheating and elevated pressure. Therefore, laminar, freely propagating 1d CH$_{4}$ flames were calculated, where oxygen content in the oxidizer (from air to pure oxy-fuel combustion), inlet temperature and pressure were varied for a wide range of the equivalence ratios. The preheat temperature and pressure were parametrically changed from 300 K to 573 K and 1 bar to 5 bar, respectively. Different reaction mechanisms were used, namely GRI30, DLR, USC/II, Caltech2.3 and ABF. The performance of the CH$_{2}$OxOH as a marker for HRR is assessed in terms of correlation coefficients of their profiles in laminar flames.
The comparison of the obtained correlations of CH$_{4}$/air and CH$_{4}$/O$_{2}$ flames shows that in case of air combustion, the HRR can be accurately estimated by the product of CH$_{2}$OxOH for slightly rich flames (Φ = 1.5), whereas the quality of the correlation degrades with increasing equivalence ratio. ... mehrIn contrary, the correlation coefficient increases with higher equivalence ratios in the fuel-rich domain for enhanced oxygen contents in the oxidizer. For pure oxyfuel combustion, the best correlation is found at an equivalence ratio of approximately Φ = 3.0. Elevated pressure leads in all flames to better correlations at lower equivalence ratios compared to standard inlet conditions, whereas preheating induces the opposite trend and expands the valid regime.
A series of CH$_{4}$/air flames were also investigated experimentally in a range of the equivalence ratio between 1 < Φ < 2 at standard inlet conditions. The qualitative CH$_{2}$O (excitation at 355 nm) and OH (excitation at 283 nm) concentration were resolved applying two-dimensional LIF for flames stabilized at a McKenna burner. Comparisons show similar trends for measurements and numerical simulations.