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Assembly of Molecular Building Blocks into Integrated Complex Functional Molecular Systems: Structuring Matter Made to Order

Hassan, Z.; Matt, Y.; Begum, S.; Tsotsalas, M.; Bräse, S.

Abstract:
Function-inspired design of molecular building blocks for their assembly into complex systems has been an objective in engineering nanostructures and materials modulation at nanoscale. This article summarizes recent research and inspiring progress in the design/synthesis of various custom-made chiral, switchable, and highly responsive molecular building blocks for the construction of diverse covalent/noncovalent assemblies with tailored topologies, properties, and functions. Illustrating the judicious selection of building blocks, orthogonal functionalities, and innate physical/chemical properties that bring diversity and complex functions once reticulated into materials, special focus is given to their assembly into porous crystalline networks such as metal/covalent–organic frameworks (MOFs/COFs), surface-mounted frameworks (SURMOFs), metal–organic cages/rings (MOCs), cross-linked polymer gels, porous organic polymers (POPs), and related architectures that find diverse applications in life science and various other functional materials. Smart and stimuli-responsive or dynamic building blocks, once embedded into materials, can be remotely modulated by external stimuli (light, electrons, chemicals, or mechanical forces) for controlling the structure and properties, thus being applicable for dynamic photochemical and mechanochemical control in constructing new forms of matter made to order. ... mehr

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Originalveröffentlichung
DOI: 10.1002/adfm.201907625
Scopus
Zitationen: 5
Web of Science
Zitationen: 7
Zugehörige Institution(en) am KIT Institut für Organische Chemie (IOC)
Institut für Funktionelle Grenzflächen (IFG)
3D Matter Made to Order (3DMM2O)
Institut für Biologische und Chemische Systeme (IBCS)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2020
Sprache Englisch
Identifikator ISSN: 1057-9257, 1099-0712, 1616-301X, 1616-3028
KITopen-ID: 1000105361
HGF-Programm 47.01.01 (POF III, LK 01)
Biol.Netzwerke u.Synth.Regulat. ITG+ITC
Erschienen in Advanced functional materials
Seiten 1907625
Vorab online veröffentlicht am 09.01.2020
Nachgewiesen in Web of Science
Scopus
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