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Sublimable Spin Crossover Complexes: From Spin-State Switching to Molecular Devices

Ruben, Mario; Kumar, Kuppusamy Senthil

Abstract:
Spin‐crossover (SCO) active transition metal complexes are an important class of switchable molecular materials due to their bistable spin‐state switching characteristics at or around room temperature. Vacuum‐sublimable SCO complexes are a subclass of SCO complexes suitable for fabricating ultraclean spin‐switchable films desirable for applications, especially in molecular electronics/spintronics. Consequently, on‐surface SCO of thin‐films of sublimable SCO complexes have been studied employing spectroscopy and microscopy techniques, and results of fundamental and technological importance have been obtained. This Review provides complete coverage of advances made in the field of vacuum‐sublimable SCO complexes: progress made in the design and synthesis of sublimable functional SCO complexes, on‐surface SCO of molecular and multilayer thick films, and various molecular and thin‐film device architectures based on the sublimable SCO complexes.

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Verlagsausgabe §
DOI: 10.5445/IR/1000105970
Veröffentlicht am 27.01.2021
Originalveröffentlichung
DOI: 10.1002/ANIE.201911256
Scopus
Zitationen: 22
Web of Science
Zitationen: 21
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Nanotechnologie (INT)
Institut für Quantenmaterialien und -technologien (IQMT)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2019
Sprache Englisch
Identifikator ISSN: 1433-7851
KITopen-ID: 1000105970
HGF-Programm 43.21.04 (POF III, LK 01) Molecular Engineering
Erschienen in Angewandte Chemie / International edition
Verlag Wiley
Vorab online veröffentlicht am 26.11.2019
Schlagwörter magnetic properties, molecular electronics, spin crossover, thin films
Nachgewiesen in Scopus
Web of Science
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