Ionic-liquid-based synthesis of GaN nanoparticles
Abstract:
GaN nanoparticles, 3–8 nm in diameter, are prepared by a microwave-assisted reaction of GaCl3 and KNH2 in ionic liquids. Instantaneously after the liquid-phase synthesis, the β-GaN nanoparticles are single-crystalline. The band gap is blue-shifted by 0.6 eV in comparison to bulk-GaN indicating quantum confinement effects. The GaN nanoparticles show intense green emission with a quantum yield of 55 ± 3%.
| Zugehörige Institution(en) am KIT | Institut für Anorganische Chemie (AOC) Laboratorium für Elektronenmikroskopie (LEM) Universität Karlsruhe (TH) – Zentrale Einrichtungen (Zentrale Einrichtungen) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2020 |
| Sprache | Englisch |
| Identifikator | ISSN: 1359-7345, 1364-548X KITopen-ID: 1000117608 |
| Erschienen in | Chemical communications |
| Verlag | Royal Society of Chemistry (RSC) |
| Band | 56 |
| Heft | 15 |
| Seiten | 2312–2315 |
| Nachgewiesen in | Dimensions Web of Science Scopus |