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On the fate of oxygenated organic molecules in atmospheric aerosol particles

Pospisilova, V.; Lopez-Hilfiker, F. D.; Bell, D. M.; El Haddad, I.; Mohr, C.; Huang, W.; Heikkinen, L.; Xiao, M.; Dommen, J.; Prevot, A. S. H.; Baltensperger, U.; Slowik, J. G.

Abstract:
Highly oxygenated organic molecules (HOMs) are formed from the oxidation of biogenic and anthropogenic gases and affect Earth’s climate and air quality by their key role in particle formation and growth. While the formation of these molecules in the gas phase has been extensively studied, the complexity of organic aerosol (OA) and lack of suitable measurement techniques have hindered the investigation of their fate post-condensation, although further reactions have been proposed. We report here novel real-time measurements of these species in the particle phase, achieved using our recently developed extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF). Our results reveal that condensed-phase reactions rapidly alter OA composition and the contribution of HOMs to the particle mass. In consequence, the atmospheric fate of HOMs cannot be described solely in terms of volatility, but particle-phase reactions must be considered to describe HOM effects on the overall particle life cycle and global carbon budget.

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Originalveröffentlichung
DOI: 10.1126/sciadv.aax8922
Scopus
Zitationen: 3
Web of Science
Zitationen: 2
Zugehörige Institution(en) am KIT Institut für Meteorologie und Klimaforschung - Atmosphärische Aerosolforschung (IMK-AAF)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2020
Sprache Englisch
Identifikator ISSN: 2375-2548
KITopen-ID: 1000118232
HGF-Programm 12.03.03 (POF III, LK 01) Gas to particle conversion
Erschienen in Science advances
Verlag American Association for the Advancement of Science (AAAS)
Band 6
Heft 11
Seiten eaax8922
Externe Relationen Abstract/Volltext
Nachgewiesen in Scopus
Web of Science
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