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On the chemical and microstructural requirements for the pesting-resistance of Mo-Si-Ti alloys

Obert, Susanne; Kauffmann, Alexander; Seils, Sascha; Schellert, Steven; Weber, Matthias; Gorr, Bronislava; Christ, Hans-Jürgen; Heilmaier, Martin

Abstract (englisch):
In recent publications [Schliephake et al. in Intermetallics 104 (2019) 133-142 and Obert, Kauffmann & Heilmaier in Acta Materialia, 184 (2020) 132-142], an unexpected pesting-stability of fully eutectic and specific eutectic-eutectoid Mo-Si-Ti alloys was found. Several potential reasons were proposed: microstructural length scale being typically very fine due to the eutectic and eutectoid reactions, the phase distribution including the fraction of the eutectic and eutectoid regions, as well as the chemical composition of the individual phases. In the present study, we prove the Ti content to be decisive for the pesting-resistance in air at 800 °C by investigating the microstructure and oxidation behaviour of Mo-Si-Ti alloys with systematically varying nominal Ti content. A critical Ti content of 43 at% was identified. Due to the phase equilibrium, this corresponds to a local Ti content in Mo solid solution of 35 at%. Other microstructural properties such as (i) lamellar size within eutectic and eutectoid regions and (ii) volume fraction of the eutectic and eutectoid regions were demonstrated to have an insignificant influence on the pesting-resistance of the alloys. ... mehr

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Verlagsausgabe §
DOI: 10.5445/IR/1000120019/pub
Veröffentlicht am 16.06.2020
Originalveröffentlichung
DOI: 10.1016/j.jmrt.2020.06.002
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Angewandte Materialien - Werkstoffkunde (IAM-WK)
Karlsruhe Nano Micro Facility (KNMF)
Graduiertenkolleg 2561: Materials Compounds from Composite Materials (GRK 2561)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2020
Sprache Englisch
Identifikator ISSN: 2214-0697, 2238-7854
KITopen-ID: 1000120019
HGF-Programm 34.13.02 (POF III, LK 01) Portfolio Material zukünftige Energief.
Erschienen in Journal of materials research and technology
Verlag Elsevier
Band 9
Heft 4
Seiten 8556–8567
Bemerkung zur Veröffentlichung Gefördert durch den KIT-Publikationsfonds
Vorab online veröffentlicht am 13.06.2020
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