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In situ Activation of Bimetallic Pd−Pt Methane Oxidation Catalysts

Karinshak, K. A. 1; Lott, P. ORCID iD icon 1; Harold, M. P.; Deutschmann, O. ORCID iD icon 1
1 Institut für Technische Chemie und Polymerchemie (ITCP), Karlsruher Institut für Technologie (KIT)

Abstract (englisch):

This study investigates possible pathways to reduce water inhibition over Pd−Pt methane oxidation catalysts supported on alumina and a ceria‐zirconia mixed oxide under conditions typical for lean burn gas engines. Spatially resolved concentration and temperature profiles reveal that addition of hydrogen to the lean reaction mixture leads to significant heat production and an increase in methane conversion. Moreover, reductive pulses during operation are not only able to regenerate the catalyst deactivated by water by removal of OH‐groups from the catalyst surface, but even promote its activity after repeated application of pulsing for several hours. X‐ray absorption spectroscopy reveals the formation of a partially reduced PdO−Pd mixture during the pulsing, which explains the increase in activity. This state of high activity is stable for several hours under the tested lean conditions. The results presented in this study suggest an efficient in situ activation strategy to overcome water inhibition of methane total oxidation over Pd−Pt catalysts by careful process control.

Verlagsausgabe §
DOI: 10.5445/IR/1000120998
Veröffentlicht am 23.11.2021
DOI: 10.1002/cctc.202000603
Zitationen: 32
Zitationen: 37
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Technische Chemie und Polymerchemie (ITCP)
Publikationstyp Zeitschriftenaufsatz
Publikationsdatum 21.07.2020
Sprache Englisch
Identifikator ISSN: 1867-3880, 1867-3899
KITopen-ID: 1000120998
Erschienen in ChemCatChem
Verlag Wiley-VCH Verlag
Band 12
Heft 14
Seiten 3712-3720
Vorab online veröffentlicht am 13.04.2020
Nachgewiesen in Scopus
Web of Science
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