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Ink Formulation for Printed Organic Electronics: Investigating Effects of Aggregation on Structure and Rheology of Functional Inks Based on Conjugated Polymers in Mixed Solvents

Schlisske, S.; Rosenauer, C.; Rödlmeier, T.; Giringer, K.; Michels, J. J.; Kremer, K.; Lemmer, U.; Morsbach, S.; Daoulas, K. C.; Hernandez-Sosa, G.

Abstract:
The utilization of solution‐processable organic semiconducting (OSC) polymers and the development of industrial‐relevant printing techniques enable cost‐efficient fabrication of optoelectronic devices for the mass market. Yet, the adaptation of viscoelastic properties of a functional ink to the respective printing technology is challenging. One crucial parameter is the formulation of the ink, which can be adjusted by selecting the combination of solvents that are mixed with the OSC. The current study considers model functional inks composed of a poly‐phenylene‐vinylene‐based OSC and two solvents, empirically known to be good. Their quality is quantified using the Hansen solubility parameters. The influence of the composition of the solvent mixture on structural, dynamical, and rheological behavior of the ink is investigated with light scattering, viscometry, and rheometry. Although both solvents are considered good, polymer aggregation is found at all compositions. Aggregation depends on composition in a nontrivial way. For dilute and semi‐dilute inks, the effects of aggregates on the ink viscosity are hidden by the difference in viscosities of the neat solvents. ... mehr

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Verlagsausgabe §
DOI: 10.5445/IR/1000122745
Veröffentlicht am 29.08.2020
Originalveröffentlichung
DOI: 10.1002/admt.202000335
Scopus
Zitationen: 1
Web of Science
Zitationen: 2
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Mikrostrukturtechnik (IMT)
Lichttechnisches Institut (LTI)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2020
Sprache Englisch
Identifikator ISSN: 2365-709X
KITopen-ID: 1000122745
HGF-Programm 43.23.04 (POF III, LK 01) Nanophotonics for Energy Conversion
Erschienen in Advanced materials technologies
Verlag Wiley
Vorab online veröffentlicht am 28.06.2020
Nachgewiesen in Web of Science
Scopus
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