A bis(germylene) functionalized metal-coordinated polyphosphide and its isomerization
Abstract:
Pentaphosphaferrocene, [Cp*Fe(η$^{5}$-P$_{5}$)] (Cp* = η$^{5}$-C$_{5}$Me$_{5}$), was used as a polyphosphorus source to obtain germylene–polyphosphide complexes. A stepwise reactivity was observed between the di-germylene, [LGe–GeL] (L = {PhC(N$^{t}$Bu)$_{2}$}), and [Cp*Fe(η$^{5}$-P$_{5}$)]. Firstly, reductive homolytic cleavage of the Ge–Ge single bond in [LGe–GeL] led to [(LGe)$_{2}${(μ,η$^{4}$-P$_{5}$)FeCp*}]. This complex showed an unprecedented isomerization.
| Zugehörige Institution(en) am KIT | Institut für Anorganische Chemie (AOC) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsdatum | 11.09.2020 |
| Sprache | Englisch |
| Identifikator | ISSN: 0009-241X, 0022-4936, 1359-7345, 1364-548X, 2050-5620, 2050-5639 KITopen-ID: 1000124100 |
| Erschienen in | Chemical communications |
| Verlag | Royal Society of Chemistry (RSC) |
| Band | 56 |
| Heft | 70 |
| Seiten | 10207-10210 |
| Vorab online veröffentlicht am | 04.08.2020 |
| Externe Relationen | Abstract/Volltext |
| Nachgewiesen in | Dimensions Scopus Web of Science |