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Triptycene End‐Capped Benzothienobenzothiophene and Naphthothienobenzothiophene

Ueberricke, Lucas; Schwarz, Julia; Ghalami, Farhad 1; Matthiesen, Maik; Rominger, Frank; Elbert, Sven M.; Zaumseil, Jana; Elstner, Marcus 1; Mastalerz, Michael
1 Institut für Physikalische Chemie (IPC), Karlsruher Institut für Technologie (KIT)


Previously it was demonstrated that triptycene end‐capping can be used as a crystal engineering strategy to direct the packing of quinoxalinophenanthrophenazines (QPPs) towards cofacially stacked π dimers with large molecular overlap resulting in high charge transfer integrals. Remarkably, this packing motif was formed under different crystallization conditions and with a variety of derivatives bearing additional functional groups or aromatic substituents. Benzothienobenzothiophene (BTBT) and its derivatives are known as some of the best performing compounds for organic field‐effect transistors. Here, the triptycene end‐capping concept is introduced to this class of compounds and polymorphic crystal structures are investigated to evaluate the potential of triptycene end‐caps as synthons for crystal engineering.

Verlagsausgabe §
DOI: 10.5445/IR/1000124432
Veröffentlicht am 13.10.2020
DOI: 10.1002/chem.202001125
Zitationen: 4
Zitationen: 4
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Physikalische Chemie (IPC)
Publikationstyp Zeitschriftenaufsatz
Publikationsdatum 01.10.2020
Sprache Englisch
Identifikator ISSN: 0947-6539, 1521-3765
KITopen-ID: 1000124432
Erschienen in Chemistry - a European journal
Verlag John Wiley and Sons
Band 26
Heft 55
Seiten 12596–12605
Vorab online veröffentlicht am 11.09.2020
Nachgewiesen in Scopus
Web of Science
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