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Surface Modification Strategies for Improving the Cycling Performance of Ni-Rich Cathode Materials – Surface Modification Strategies for Improving the Cycling Performance of Ni-Rich Cathode Materials

Weber, Daniel 1,2; Tripković, Đorđije 1,2; Kretschmer, Katja 1,2; Bianchini, Matteo 1,2; Brezesinski, Torsten ORCID iD icon 1,2
1 Institut für Nanotechnologie (INT), Karlsruher Institut für Technologie (KIT)
2 Center for Electrochemical Energy Storage Ulm & Karlsruhe (CELEST), Karlsruher Institut für Technologie (KIT)


Ni‐rich layered lithium metal oxides are the cathode active materials of choice for high‐energy‐density Li‐ion batteries. While the high content of Ni is responsible for the excellent capacity, it is also the source of interfacial instability, limiting the material's lifetime due to a variety of correlated in‐ and extrinsic factors. Hence, reconciling the opposing trends of high Ni content and long‐term cycling stability by modifying the material's surface is one of the challenges in the field. Here, we review various studies on surface modification of Ni‐rich (≥ 80 %) layered cathode active materials in order to categorize current research efforts. Broadly, the three strategies of coating, surface doping and washing are discussed, each with their advantages and shortcomings. In conclusion, we highlight new directions of research that could bring Ni‐rich layered lithium metal oxide cathodes from the laboratory to the real world.

Verlagsausgabe §
DOI: 10.5445/IR/1000124604
Veröffentlicht am 14.10.2020
DOI: 10.1002/ejic.202000408
Zitationen: 50
Web of Science
Zitationen: 50
Zitationen: 49
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Nanotechnologie (INT)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2020
Sprache Englisch
Identifikator ISSN: 1434-1948
KITopen-ID: 1000124604
HGF-Programm 37.01.01 (POF III, LK 01) Fundamentals and Materials
Erschienen in European journal of inorganic chemistry
Verlag Wiley-VCH Verlag
Band 2020
Heft 33
Seiten 3117-3130
Vorab online veröffentlicht am 28.07.2020
Nachgewiesen in Scopus
Web of Science
Globale Ziele für nachhaltige Entwicklung Ziel 7 – Bezahlbare und saubere Energie
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