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Composition and structure of magnetic high-temperature-phase, stable Fe-Au core-shell nanoparticles with zero-valent bcc Fe core

Kamp, M.; Tymoczko, A.; Popescu, Radian 1; Schürmann, U.; Nadarajah, R.; Gökce, B.; Rehbock, C.; Gerthsen, Dagmar 1; Barcikowski, S.; Kienle, L.
1 Laboratorium für Elektronenmikroskopie (LEM), Karlsruher Institut für Technologie (KIT)

Abstract:

Advanced quantitative TEM/EDXS methods were used to characterize different ultrastructures of magnetic Fe–Au core–shell nanoparticles formed by laser ablation in liquids. The findings demonstrate the presence of Au-rich alloy shells with varying composition in all structures and elemental bcc Fe cores. The identified structures are metastable phases interpreted by analogy to the bulk phase diagram. Based on this, we propose a formation mechanism of these complex ultrastructures. To show the magnetic response of these magnetic core nanoparticles protected by a noble metal shell, we demonstrate the formation of nanostrands in the presence of an external magnetic field. We find that it is possible to control the lengths of these strands by the iron content within the alloy nanoparticles.


Verlagsausgabe §
DOI: 10.5445/IR/1000125815
Veröffentlicht am 09.11.2020
Originalveröffentlichung
DOI: 10.1039/d0na00514b
Scopus
Zitationen: 13
Dimensions
Zitationen: 13
Cover der Publikation
Zugehörige Institution(en) am KIT Laboratorium für Elektronenmikroskopie (LEM)
Universität Karlsruhe (TH) – Zentrale Einrichtungen (Zentrale Einrichtungen)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2020
Sprache Englisch
Identifikator ISSN: 2516-0230
KITopen-ID: 1000125815
Erschienen in Nanoscale advances
Verlag Royal Society of Chemistry (RSC)
Band 2
Heft 9
Seiten 3912-3920
Schlagwörter 2018-019-021334 TEM
Nachgewiesen in Dimensions
Scopus
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