Synthetic access to a phosphorescent non-palindromic pincer complex of palladium by a double oxidative addition-comproportionation sequence
Abstract:
A highly luminescent non-palindromic [(C^C^N)Pd] pincer complex forms upon reacting pyridine-substituted 2,2′-diiodo-biphenyl with [Pd(PPh$_{3}$)$_{4}$]. This case study establishes for the first time that the title compound is formed via a double oxidative addition – comproportionation sequence. DFT and TDDFT calculations complement mechanistic and photophysical characterizations.
| Zugehörige Institution(en) am KIT | Institut für Anorganische Chemie (AOC) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2020 |
| Sprache | Englisch |
| Identifikator | ISSN: 0009-241X, 0022-4936, 1359-7345, 1364-548X, 2050-5620, 2050-5639 KITopen-ID: 1000126023 |
| Erschienen in | Chemical communications |
| Verlag | Royal Society of Chemistry (RSC) |
| Band | 56 |
| Heft | 83 |
| Seiten | 12589-12592 |
| Vorab online veröffentlicht am | 26.08.2020 |
| Nachgewiesen in | Dimensions Scopus Web of Science |