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Synthesis, Characterization, Electrochemistry, Photoluminescence and Magnetic Properties of a Dinuclear Erbium(III)-Containing Monolacunary Dawson-Type Tungstophosphate: [{Er(H2O)(CH3COO)(P2W17O61)}2]16−

Ibrahim, Masooma; Baksi, Ananya; Peng, Yan; Al-Zeidaneen, Firas Khalil; Mbomekallé, Israël M.; de Oliveira, Pedro; Anson, Christopher E.

Abstract:
Reaction of the trilacunary Wells−Dawson anion {α-P$_{2}$W$_{15}$O$_{56}$$^{12-}$ with ErIII ion in a 1 M LiOAc/HOAc buffer (pH 4.8) solution produces a dinuclear erbium(III) substituted sandwich-type structure [{Er(H$_{2}$O)(CH$_{3}$COO)(P$_{2}$W$_{17}$O$_{61}$)}$_{2}$]$^{16-}$ (1). The isolated compound was structurally characterized using single crystal and powder X-ray diffraction, FTIR spectroscopy, mass spectrometry and thermogravimetric analysis. The electrochemical, electrocatalytic, photoluminescence and magnetic properties of 1 were investigated.

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Verlagsausgabe §
DOI: 10.5445/IR/1000126922
Veröffentlicht am 29.11.2020
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Anorganische Chemie (AOC)
Institut für Nanotechnologie (INT)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2020
Sprache Englisch
Identifikator ISSN: 1420-3049
KITopen-ID: 1000126922
HGF-Programm 43.21.04 (POF III, LK 01) Molecular Engineering
Erschienen in Molecules
Band 25
Heft 18
Seiten Art. Nr.: 4229
Vorab online veröffentlicht am 15.09.2020
Schlagwörter polyoxometalates, catalysis, mass spectrometry, molecular magnetism, electrochemistry, lanthanide, erbium
Nachgewiesen in Scopus
Web of Science
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