KIT | KIT-Bibliothek | Impressum | Datenschutz

Designing Structurally Ordered Pt/Sn Nanoparticles in Ionic Liquids and their Enhanced Catalytic Performance

Dietrich, Christine 1; Hähsler, Martin 1; Wang, Wu 2; Kübel, Christian ORCID iD icon 2,3; Behrens, Silke 1
1 Institut für Katalyseforschung und -technologie (IKFT), Karlsruher Institut für Technologie (KIT)
2 Institut für Nanotechnologie (INT), Karlsruher Institut für Technologie (KIT)
3 Karlsruhe Nano Micro Facility (KNMF), Karlsruher Institut für Technologie (KIT)


Multimetallic nanoparticles (NPs) often exhibit enhanced catalytic properties that differ from their parent materials. Carefully exploring the structures of multimetallic NPs is a prerequisite for understanding the structure‐ and composition‐associated properties. Herein, intermetallic Pt/Sn NPs with tunable compositions are designed exploiting the beneficial properties of ionic liquids (ILs) in a one‐pot synthetic procedure. Metal salt precursors are reduced with triethylhydridoborate, whereby the cation of the triethylhydridoborate is adapted to the cation of the IL. Both the initial metal precursor ratio and the type of IL influence the structure of the NPs, with the effect of the IL being more pronounced. PtSn nanocrystals are obtained as phase pure products under optimized reaction conditions, whereby a microwave‐assisted approach leads to higher crystallinity. In the hydrogenation of α,β‐unsaturated aldehydes, the catalytic performance obviously depend on the NP composition. In bimetallic Pt/Sn NPs, higher Pt content leads to increased conversion, while increase in Sn increases selectivity to the cinnamic alcohol.

Verlagsausgabe §
DOI: 10.5445/IR/1000127050
Veröffentlicht am 01.12.2020
DOI: 10.1002/cnma.202000433
Zitationen: 7
Zitationen: 7
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Katalyseforschung und -technologie (IKFT)
Institut für Nanotechnologie (INT)
Karlsruhe Nano Micro Facility (KNMF)
Publikationstyp Zeitschriftenaufsatz
Publikationsmonat/-jahr 12.2020
Sprache Englisch
Identifikator ISSN: 2199-692X, 2199-692X
KITopen-ID: 1000127050
HGF-Programm 43.22.02 (POF III, LK 01) Nanocatalysis
Erschienen in ChemNanoMat
Verlag John Wiley and Sons
Band 6
Heft 12
Seiten 1854-1862
Vorab online veröffentlicht am 16.11.2020
Schlagwörter 2018-020-022709, TEM
Nachgewiesen in Dimensions
Web of Science
KIT – Die Forschungsuniversität in der Helmholtz-Gemeinschaft
KITopen Landing Page