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Some Aspects of Time-Reversal in Chemical Kinetics

Maas, Ulrich

Abstract:
Chemical kinetics govern the dynamics of chemical systems leading towards chemical equilibrium. There are several general properties of the dynamics of chemical reactions such as the existence of disparate time scales and the fact that most time scales are dissipative. This causes a transient relaxation to lower dimensional attracting manifolds in composition space. In this work, we discuss this behavior and investigate how a time reversal effects this behavior. For this, both macroscopic chemical systems as well as microscopic chemical systems (elementary reactions) are considered.


Verlagsausgabe §
DOI: 10.5445/IR/1000127902
Veröffentlicht am 21.12.2020
Originalveröffentlichung
DOI: 10.3390/e22121386
Web of Science
Zitationen: 1
Dimensions
Zitationen: 1
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Technische Thermodynamik (ITT)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2020
Sprache Englisch
Identifikator ISSN: 1099-4300
KITopen-ID: 1000127902
Erschienen in Entropy
Verlag MDPI
Band 22
Heft 12
Seiten Article no: 1386
Vorab online veröffentlicht am 07.12.2020
Schlagwörter chemical kinetics, time reversal, time scales, low-dimensional manifolds
Nachgewiesen in Dimensions
Web of Science
Scopus
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