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Introducing electrical conductivity to metal-organic framework thin films by templated polymerization of methyl propiolate

Sen, Beren; Santos, Jaciara C. C.; Haldar, Ritesh; Zhang, Qiang; Hashem, Tawheed; Qin, Peng; Li, Ying; Kirschhöfer, Frank; Brenner-Weiss, Gerald; Gliemann, Hartmut; Heinke, Lars; Barner-Kowollik, Christopher; Knebel, Alexander; Wöll, Christof

We herein present a case study on the templated, Pd-catalyzed polymerization reaction of methyl propiolate in the confined pore space of three different surface anchored metal–organic framework (SURMOF) systems in order to introduce electrical conductivity to MOF thin films and provide predictions for potential device integrations. To gain comprehensive insight into the influence of the template on polymerization, we chose Cu(bpdc), Cu$_{2}$(bdc)$_{2}$ (dabco) and HKUST-1 because of their different types of pore channels, 1D, quasi-1D and 3D, and their free pore volumes. Well-defined MOF thin films were prepared using layer-by-layer deposition, which allows for the application of several characterization techniques not applicable for conventional powder MOFs. With SEM, AFM, XRD, MALDI-ToF/MS, ToF-SIMS and QCM, we were able to investigate the behaviour of the polymer formation. For lower dimensional pore channels, we find a depot-like release of monomeric units leading to top-layer formation determined by desorption kinetics, whereas for the 3D channels, quick release of an excess amount of monomers was observed and polymerization proceeds perfectly. ... mehr

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Verlagsausgabe §
DOI: 10.5445/IR/1000129128
Veröffentlicht am 29.01.2021
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Funktionelle Grenzflächen (IFG)
Institut für Nanotechnologie (INT)
Publikationstyp Zeitschriftenaufsatz
Publikationsdatum 28.12.2020
Sprache Englisch
Identifikator ISSN: 2040-3364, 2040-3372
KITopen-ID: 1000129128
HGF-Programm 43.21.04 (POF III, LK 01) Molecular Engineering
Erschienen in Nanoscale
Verlag Royal Society of Chemistry (RSC)
Band 12
Heft 48
Seiten 24419–24428
Nachgewiesen in Scopus
Web of Science
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