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Molecular Magnetic Architectures: From Mononuclear to Polynuclear complexes

Suryadevara, Nithin

Abstract (englisch):
The broad field of molecular magnetic materials has potential applications in the storage and processing of the information. Despite of the enormous applications of these materials, till now, there are no suitable candidates ready for the real application. So, over the decades, plenty of research has been progressing to develop suitable candidates in the field of Spin-crossover (SCO) and single molecule magnetism (SMM). In SCO, there are several reports with large hysteresis but found to be not suitable for applications since they do not satisfy many other criteria, which include the stability of the hysteresis that should be around room temperature. At the same time, for the development of the molecular devices, the bottom-up fabrication of these functional molecules is needed. Even though most of the SCO complexes are mononuclear, significant progress has been seen towards polynuclear complexes due to their tunable properties. Molecular chirality is an additional concept that plays a key role in magnetism, particularly in spintronic applications. So introducing the concept of chirality into these polynuclear SCO complexes may result in novel magneto-optical hybrid complexes. ... mehr

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Volltext §
DOI: 10.5445/IR/1000129475
Veröffentlicht am 16.02.2021
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Nanotechnologie (INT)
Publikationstyp Hochschulschrift
Publikationsdatum 16.02.2021
Sprache Englisch
Identifikator KITopen-ID: 1000129475
Verlag Karlsruher Institut für Technologie (KIT)
Umfang 161 S.
Art der Arbeit Dissertation
Fakultät Fakultät für Chemie und Biowissenschaften (CHEM-BIO)
Institut Institut für Nanotechnologie (INT)
Prüfungsdatum 08.12.2020
Referent/Betreuer Prof. M. Ruben
Projektinformation SFB/TRR 88/2 - 3 MET (DFG, DFG KOORD, TRR 88/2 2015)
TRR 88/3 - 3MET (DFG, DFG KOORD, TRR 88/3 2019)
Schlagwörter Spin Crossover, Single Molecular magnetism, Molecular Magnetism
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