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Towards Heteroleptic Dicoordinate Cu(II) Complexes

Kaiser, Michelle; Göttlicher, Jörg; Vitova, Tonya ORCID iD icon; Hinz, Alexander

Abstract:
In this work we detail our efforts to systematically generate stable dicoordinate CuII complexes. Initial experiments via metathesis reactions of a bulky potassium carbazolide (RK) with copper(II) salts indeed yielded a stable product, RCuOTf (1). However, subsequent attempts to grasp systematic synthetic access to complexes of the type RCuX (X=monoanionic ligand) proved difficult as many of the complexes rapidly decomposed in solution. By using triflate-related ligands such as ethyl sulfate and bistriflimide, the additional dicoordinate copper complexes RCuOSO3Et (2), [RCu(THF)][Cu(NTf2)2] (3) and RCuNTf2 (4) could be isolated. Spectroscopic indications corroborate more CuI than CuII character in all RCuX derivatives.


Verlagsausgabe §
DOI: 10.5445/IR/1000131492
Veröffentlicht am 20.08.2021
Originalveröffentlichung
DOI: 10.1002/chem.202100888
Dimensions
Zitationen: 2
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Anorganische Chemie (AOC)
Institut für Nukleare Entsorgung (INE)
Institut für Photonenforschung und Synchrotronstrahlung (IPS)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2021
Sprache Englisch
Identifikator ISSN: 0947-6539, 1521-3765
KITopen-ID: 1000131492
HGF-Programm 56.12.11 (POF IV, LK 01) Materials - Quantum, Complex and Functional
Weitere HGF-Programme 32.11.01 (Vor POF, LK 01)
54.11.11 (POF IV, LK 01) Accelerator Operation, Research and Development
Erschienen in Chemistry - a European journal
Verlag John Wiley and Sons
Band 27
Heft 30
Seiten 7998-8002
Vorab online veröffentlicht am 08.04.2021
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