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Systematic study of quaternary ammonium cations for bromine sequestering application in high energy density electrolytes for hydrogen bromine redox flow batteries

Küttinger, Michael 1; Loichet Torres, Paulette A.; Meyer, Emeline; Fischer, Peter; Tübke, Jens 1
1 Institut für Mechanische Verfahrenstechnik und Mechanik (MVM), Karlsruher Institut für Technologie (KIT)

Abstract:

Bromine complexing agents (BCAs) are used to reduce the vapor pressure of bromine in the aqueous electrolytes of bromine flow batteries. BCAs bind hazardous, volatile bromine by forming a second, heavy liquid fused salt. The properties of BCAs in a strongly acidic bromine electrolyte are largely unexplored. A total of 38 different quaternary ammonium halides are investigated ex situ regarding their properties and applicability in bromine electrolytes as BCAs. The focus is on the development of safe and performant HBr/Br$_{2}$/H$_{2}$O electrolytes with a theoretical capacity of 180 Ah L$^{-1}$ for hydrogen bromine redox flow batteries (H$_{2}$/Br$_{2}$-RFB). Stable liquid fused salts, moderate bromine complexation, large conductivities and large redox potentials in the aqueous phase of the electrolytes are investigated in order to determine the most applicable BCA for this kind of electrolyte. A detailed study on the properties of BCA cations in these parameters is provided for the first time, as well as for electrolyte mixtures at different states of charge of the electrolyte. 1-ethylpyridin-1-ium bromide [C$_{2}$Py]Br is selected from 38 BCAs based on its properties as a BCA that should be focused on for application in electrolytes for H$_{2}$/Br$_{2}$-RFB in the future.


Verlagsausgabe §
DOI: 10.5445/IR/1000133844
Veröffentlicht am 14.06.2021
Originalveröffentlichung
DOI: 10.3390/molecules26092721
Scopus
Zitationen: 6
Web of Science
Zitationen: 6
Dimensions
Zitationen: 7
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Mechanische Verfahrenstechnik und Mechanik (MVM)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2021
Sprache Englisch
Identifikator ISSN: 1420-3049
KITopen-ID: 1000133844
Erschienen in Molecules
Verlag MDPI
Band 26
Heft 9
Seiten 2721
Nachgewiesen in Dimensions
Scopus
Web of Science
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