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Catalytic Hydroisomerisation of Fischer–Tropsch Waxes to Lubricating Oil and Investigation of the Correlation between Its Physical Properties and the Chemical Composition of the Corresponding Fuel Fractions

Neuner, Philipp 1; Graf, David 1; Mild, Heiko 1; Rauch, Reinhard ORCID iD icon 1
1 Karlsruher Institut für Technologie (KIT)

Abstract (englisch):

Due to environmental concerns, the role of renewable sources for petroleum-based products has become an invaluable research topic. One possibility of achieving this goal is the Fischer–Tropsch
synthesis (FTS) based on sustainable raw materials. Those materials include, but are not limited to, synthesis gas from biomass gasification or hydrogen through electrolysis powered by renewable
electricity. In recent years, the utilisation of CO2 as carbon source for FTS was one main R&D topic. This is one of the reasons for its increase in value and the removal of its label as being just exhaust
gas. With the heavy product fraction of FTS, referred to as Fischer–Tropsch waxes (FTW), being rather limited in their application, catalytic upgrading can help to increase the economic viability of such a process by converting the waxes to high value transportation fuels and lubricating oils. In this paper, the dewaxing of FTW via hydroisomerisation and hydrocracking was investigated. A three phase fixed bed reactor was used in combination with a zeolitic catalyst with an AEL (SAPO-11) structure and 0.3 wt% platinum (Pt). The desired products were high quality white oils with low cloud points. ... mehr


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Originalveröffentlichung
DOI: 10.3390/en14144202
Scopus
Zitationen: 1
Web of Science
Zitationen: 1
Dimensions
Zitationen: 3
Zugehörige Institution(en) am KIT Engler-Bunte-Institut (EBI)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2021
Sprache Englisch
Identifikator ISSN: 1996-1073
KITopen-ID: 1000135375
HGF-Programm 38.05.01 (POF IV, LK 01) Anthropogenic Carbon Cycle
Erschienen in Energies
Verlag MDPI
Band 14
Heft 14
Seiten Art.: 4202
Bemerkung zur Veröffentlichung This article belongs to the Special Issue Catalytic Processes for CO2 Utilization.
Vorab online veröffentlicht am 12.07.2021
Schlagwörter catalytic dewaxing; hydroprocessing; lubricant production; Fischer-Tropsch
Nachgewiesen in Scopus
Web of Science
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