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Versatile Heteroleptic Cu(I) Complexes Based on Quino(xa)-line-Triazole Ligands: from Visible-Light Absorption and Cooperativity to Luminescence and Photoredox Catalysis

Bruschi, Cecilia ORCID iD icon 1; Gui, Xin 2; Salaeh-arae, Nasrin 1; Barchi, Tobia 1; Fuhr, Olaf ORCID iD icon 3,4; Lebedkin, Sergei 3; Klopper, Wim ORCID iD icon 2; Bizzarri, Claudia 1
1 Institut für Organische Chemie (IOC), Karlsruher Institut für Technologie (KIT)
2 Karlsruher Institut für Technologie (KIT)
3 Institut für Nanotechnologie (INT), Karlsruher Institut für Technologie (KIT)
4 Karlsruhe Nano Micro Facility (KNMF), Karlsruher Institut für Technologie (KIT)

Abstract:

Four new heteroleptic Cu(I) complexes based on 1, 2, 3-triazolyl-quinoline or quinoxaline and a chelating diphosphine were prepared and fully characterised. The mononuclear derivatives absorb in the visible region, up to 600 nm, while the dinuclear complex has a long-tail absorption up to 800 nm, showing an additional electronic state corroborated by theoretical calculations. Although a methylene group between the triazole and the quino(xa)line moiety increases the bite angle and decreases the luminescence in solution, all complexes emit brightly in the solid-state. Their redox properties in the excited state were determined, proving their ability in serving as photoredox catalysts in atom transfer radical addition successfully.


Verlagsausgabe §
DOI: 10.5445/IR/1000137492
Veröffentlicht am 21.09.2021
Originalveröffentlichung
DOI: 10.1002/ejic.202100653
Scopus
Zitationen: 10
Dimensions
Zitationen: 9
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Nanotechnologie (INT)
Institut für Organische Chemie (IOC)
Institut für Physikalische Chemie (IPC)
Karlsruhe Nano Micro Facility (KNMF)
Publikationstyp Zeitschriftenaufsatz
Publikationsdatum 21.10.2021
Sprache Englisch
Identifikator ISSN: 1434-1948, 0009-2940, 0365-947X, 0365-9488, 0365-9496, 1099-0682, 1434-2421
KITopen-ID: 1000137492
HGF-Programm 43.32.01 (POF IV, LK 01) Molecular Materials Basis for Optics & Photonics
Erschienen in European Journal of Inorganic Chemistry
Verlag Wiley-VCH Verlag
Band 2021
Heft 39
Seiten 4074-4084
Vorab online veröffentlicht am 03.08.2021
Nachgewiesen in Scopus
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Web of Science
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