KIT | KIT-Bibliothek | Impressum | Datenschutz

Combining Quinone‐Based Cathode with an Efficient Borate Electrolyte for High‐Performance Magnesium Batteries

Xiu, Yanlei; Li, Zhenyou; Bhaghavathi Parambath, Vinayan; Ding, Ziming 1; Wang, Liping; Reupert, Adam; Fichtner, Maximilian 1; Zhao-Karger, Zhirong
1 Karlsruher Institut für Technologie (KIT)


Rechargeable magnesium batteries are gaining attention as promising candidates for large-scale energy storage applications because of their potentially high energy, safety and sustainability. However, the development of Mg batteries is impeded by the lack of efficient cathode materials and compatible electrode-electrolyte combinations. Herein, we demonstrate a new poly(1,4-anthraquinone)/Ketjenblack composite (14PAQ@KB) in combination with non-corrosive magnesium tetrakis(hexafluoroisopropyloxy) borate Mg[B(hfip)(4)](2) (hfip=OC(H)(CF3)(2)) electrolyte towards high-energy and long-lifespan Mg batteries. This combination exhibits prominent electrochemical performance including a maximum discharge capacity of 242 mA h g(-1) (approximately 93 % of the theoretical capacity), superior cycling stability (81 mA h g(-1) after 1000 cycles), and excellent rate capability (120 mA h g(-1) at 5 C).

Verlagsausgabe §
DOI: 10.5445/IR/1000138417
Veröffentlicht am 01.10.2021
DOI: 10.1002/batt.202100163
Zitationen: 24
Web of Science
Zitationen: 24
Zitationen: 28
Cover der Publikation
Zugehörige Institution(en) am KIT Helmholtz-Institut Ulm (HIU)
Institut für Nanotechnologie (INT)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2021
Sprache Englisch
Identifikator ISSN: 2566-6223, 2566-6223
KITopen-ID: 1000138417
HGF-Programm 38.02.01 (POF IV, LK 01) Fundamentals and Materials
Erschienen in Batteries & supercaps
Verlag John Wiley and Sons
Band 4
Heft 12
Seiten 1850-1857
Vorab online veröffentlicht am 21.09.2021
Nachgewiesen in Dimensions
Web of Science
KIT – Die Forschungsuniversität in der Helmholtz-Gemeinschaft
KITopen Landing Page