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Investigation of the Coordination Chemistry of a Bisamidinate Ferrocene Ligand with Cu, Ag, and Au

Dahlen, Milena 1; Vázquez Quesada, Juana 2; Santos Correa, Luis 1; Münzfeld, Luca 1; Reinfandt, Niklas 1; Klopper, Wim ORCID iD icon 2; Roesky, Peter W. 1
1 Karlsruher Institut für Technologie (KIT)
2 Institut für Physikalische Chemie (IPC), Karlsruher Institut für Technologie (KIT)

Abstract:

The coordination chemistry of a ferrocene ligand with one bulky amidinate function attached to each ring toward two different coinage metal precursors was investigated. In dependence of the metal and the co-ligands, “ansa” type structures and non-bridged structures were obtained. Six different compounds are reported. In the “ansa” type structures, short Fe–M (M = Cu, Ag) distances were observed in the molecular structures in the solid state. However, theoretical calculations (DFT) did not reveal a stabilizing metal–metal interaction. Instead, dispersion interactions within the ligand and between the ligand and metal seem to represent the main stabilization forces.


Verlagsausgabe §
DOI: 10.5445/IR/1000143112
Veröffentlicht am 16.02.2022
Originalveröffentlichung
DOI: 10.1021/acsomega.1c07036
Scopus
Zitationen: 1
Web of Science
Zitationen: 1
Dimensions
Zitationen: 1
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Physikalische Chemie (IPC)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2021
Sprache Englisch
Identifikator ISSN: 2470-1343
KITopen-ID: 1000143112
HGF-Programm 43.32.01 (POF IV, LK 01) Molecular Materials Basis for Optics & Photonics
Erschienen in ACS Omega
Verlag American Chemical Society (ACS)
Band 7
Heft 5
Seiten 4683–4693
Bemerkung zur Veröffentlichung Gefördert durch den KIT-Publikationsfonds
Nachgewiesen in Scopus
Web of Science
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